Off the bat, what I found right away after following the link to the post, was an AI video. Many people in the comments responded saying it was AI, quick to put a stop to the misleading video. Despite the video itself being AI, that doesn't necessarily mean that the overall claim is necessarily untrue. One of the people in the comments linked an article that I followed up on, and right away noticed it was from a reliable source. The source was Smithsonian Magazine, and when I googled its reliability, on a scale of 60 total points of reliability, it was given a 45.3 meaning that it is reliable and that they practice analysis/fact reporting.
This article came out in 2022 and at the time this was supposedly the first time that this sort of behavior was documented by scientists amongst tentacled sea creatures. One key difference between the headline posted in the initial claim seeking to be fact checked is that it was a rock being hurled, an object that is heavier. Naturally it is clear that it was AI, in that it was thrown like a baseball, something clearly not feasible, but what about a more realistic item that could be thrown, or at least tossed? In this article they provide a non AI video example, which is one octopus throwing a shell at another. Not only does it show this, but it explains the behavior for why they would do this, making it more believable, but also more factual and educational. Some things they throw at each other include algae, silt, and shells, much lighter than a baseball sized rock. This source also provided some statistics, "they noted 102 instances of throwing among roughly ten individuals. Two females made 66 percent of the throws, which tracks with past research that found female octopuses throw objects at males when they’re feeling harassed".
To provide further information to how this claim is misleading is the word "throw". The Smithsonian article elaborates on this as well: "'Throwing,' however, may not be the most accurate word to describe the octopuses’ behavior. With their arms, the creatures gathered silt underneath their bodies, then used an appendage known as a siphon to violently expel water and send the debris flying. This maneuver required them to move their siphon into an unusual position, which researchers say suggests they were doing it deliberately."
Lastly to go one step further, one of the Smithsonian's primary source was a journal called PLOS One. A google search told me that this journal is legitimate, reputable, peer-reviewed meaning that it is reliable. Given the peer reviewed nature, if this source was biased, that likely would have been pointed out in the peer review process, and had it reworked before being published. Additionally since the Smithsonian magazine's goal is to educate the population on science and so no, they have a vested interest in making the information they share true. The website that provided info on their reliability before also stated them as a middle bias.
Overall, female octopi do participate in this sort of behavior, but to say they "throw" is overall is a misleading and exaggerated claim.
Links:
https://www.smithsonianmag.com/smart-news/octopuses-caught-on-camera-throwing-debris-at-each-other-180981109/
https://journals.plos.org/plosone/article?id=10.1371/journal.pone.0276482
https://adfontesmedia.com/smithsonian-magazine-bias-and-reliability/